All elements either emit or absorb certain frequencies of light. Evidence from atomic line spectra supports the Bohr model of the atom using photon frequency calculations.
A free atom is one which experiences no forces from neighbouring atoms.
The Bohr model (named after Danish physicist Niels Bohr) of an atom has a small, positively charged central nucleus and electrons orbiting in at specific fixed distances from the nucleus.
Electrons are not allowed to orbit in the space between these specific fixed orbits. Each of these orbits has an energy level associated with it.
The diagram shows the allowed orbits and energy levels for a hydrogen atom.
The lowest energy level is called the ground state.
If an electron gains energy it can move to a higher energy level. It is now in an excited state.
If the electron gains enough energy to completely remove it from the atom it is said to be in an ionisation state.